<!DOCTYPE html>
<html class="client-nojs vector-feature-language-in-header-enabled vector-feature-language-in-main-page-header-disabled vector-feature-page-tools-pinned-disabled vector-feature-toc-pinned-clientpref-0 vector-toc-not-available vector-feature-main-menu-pinned-disabled vector-feature-limited-width-clientpref-1 vector-feature-limited-width-content-enabled vector-feature-custom-font-size-clientpref-1 vector-feature-appearance-pinned-clientpref-0 skin-theme-clientpref-day vector-sticky-header-enabled" lang="de" dir="ltr"><head>
<meta charset="UTF-8">
<title>Boroxin</title>
<meta name="viewport" content="width=device-width, initial-scale=1.0">
<link rel="icon" type="image/png" href="./_res_/favicon.png">
<link rel="canonical" href="https://de.wikipedia.org/wiki/Boroxin"> <link href="./_mw_/ext.cite.styles.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.wikimediamessages.styles.css" rel="stylesheet" type="text/css">
<link href="./_mw_/skins.vector.icons.css" rel="stylesheet" type="text/css">
<link href="./_mw_/skins.vector.search.codex.styles.css" rel="stylesheet" type="text/css">
<link href="./_mw_/skins.vector.styles.css" rel="stylesheet" type="text/css">
<meta name="ResourceLoaderDynamicStyles" content="">
<link href="./_mw_/ext.gadget.citeRef.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.defaultPlainlinks.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.dewikiCommonHide.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.dewikiCommonLayout.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.dewikiCommonStyle.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.dewikiDarkmode.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.dewikiResponsive.css" rel="stylesheet" type="text/css">
<link href="./_mw_/ext.gadget.specialSearch.css" rel="stylesheet" type="text/css">
<link rel="stylesheet" type="text/css" href="./_mw_/site.styles.css">
<link rel="stylesheet" type="text/css" href="./_mw_/noscript.css">
<link rel="stylesheet" type="text/css" href="./_res_/footer.css">
<link rel="stylesheet" type="text/css" href="./_res_/vector-2022.css">
</head>
<body class="skin--responsive skin-vector skin-vector-search-vue mediawiki ltr sitedir-ltr mw-hide-empty-elt ns-0 ns-subject page-Boroxin rootpage-Boroxin skin-vector-2022 action-view">
<div class="mw-page-container">
<div class="mw-page-container-inner">
<div class="mw-content-container">
<main id="content" class="mw-body">
<header class="mw-body-header vector-page-titlebar">
<h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Boroxin</span></h1>
</header>
<a id="top"></a>
<div id="bodyContent" class="vector-body ve-init-mw-desktopArticleTarget-targetContainer" aria-labelledby="firstHeading" data-mw-ve-target-container="">
<div id="contentSub">
<div id="mw-content-subtitle"></div>
</div>
<div id="mw-content-text" class="mw-body-content mw-content-ltr" lang="de" dir="ltr"><div class="mw-content-ltr mw-parser-output" lang="de" dir="ltr"><table class="wikitable infobox float-right" id="Vorlage_Infobox_Chemikalie" style="font-size:90%; margin-top:0; width:350px;" summary="Infobox Chemikalie">
<tbody><tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Strukturformel
</th></tr>
<tr>
<td colspan="2" class="hintergrundfarbe-basis skin-invert-image" style="text-align:center;"><span typeof="mw:File"></span>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Allgemeines
</th></tr>
<tr>
<td style="width:33%;">Name
</td>
<td>Boroxin
</td></tr>
<tr>
<td>Andere Namen
</td>
<td>
<ul><li>Cyclotriboroxan</li>
<li>1,3,5,2,4,6-trioxatriborinane</li></ul>
</td></tr>
<tr>
<td><a href="Summenformel" title="Summenformel">Summenformel</a>
</td>
<td>B<sub>3</sub>H<sub>3</sub>O<sub>3</sub>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Externe Identifikatoren/Datenbanken
</th></tr>
<tr>
<td colspan="2" style="padding:0;">
<table class="mw-collapsible mw-collapsed wikitable" data-expandtext="+" data-collapsetext="−" style="border-top:none; margin:-1px; width:calc(100% + 2px);">
<tbody><tr>
<td style="width:33%;"><a href="CAS-Nummer" title="CAS-Nummer">CAS-Nummer</a>
</td>
<td><span title="Untervorlage eingebunden: CASRN"></span><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=289-56-5">289-56-5</a><span class="editoronly" style="display:none;"></span>
</td>
<td style="background:#FFDEAD; color:#202122; border-top:1px solid #FFDEAD; padding:0.2em 0; vertical-align:bottom; width:5%;">
</td></tr>
<tr>
<td><a href="PubChem" title="PubChem">PubChem</a>
</td>
<td colspan="2"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/136134">136134</a>
</td></tr>
<tr>
<td><a href="ChemSpider" title="ChemSpider">ChemSpider</a>
</td>
<td colspan="2"><a rel="nofollow" class="external text" href="https://www.chemspider.com/Chemical-Structure.119911.html">119911</a>
</td></tr>
<tr>
<td style="border-right:1px solid #a2a9b1;"><a href="Wikidata" title="Wikidata">Wikidata</a>
</td>
<td colspan="2"><a href="https://www.wikidata.org/wiki/Q894130" class="extiw external" title="d:Q894130">Q894130</a>
</td></tr></tbody></table>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Eigenschaften
</th></tr>
<tr>
<td><a href="Molare_Masse" title="Molare Masse">Molare Masse</a>
</td>
<td>83,45 <a href="Gramm" title="Gramm">g</a>·<a href="Mol" title="Mol">mol</a><sup>−1</sup>
</td></tr>
<tr>
<th colspan="2" style="background:#FFDEAD; color:#202122;">Sicherheitshinweise
</th></tr>
<tr>
<td colspan="2">
<table cellspacing="0" cellpadding="2" style="width:100%;">
<tbody><tr>
<td colspan="2" style="text-align:center"><b><a href="Global_harmonisiertes_System_zur_Einstufung_und_Kennzeichnung_von_Chemikalien" title="Global harmonisiertes System zur Einstufung und Kennzeichnung von Chemikalien">GHS-Gefahrstoffkennzeichnung</a></b><br><i>keine Einstufung verfügbar</i><sup id="cite_ref-NV_1-0" class="reference"><a href="#cite_note-NV-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>
</td></tr></tbody></table>
</td></tr>
<tr>
<td colspan="2" style="background:#FFDEAD; color:#202122; font-size:80%; text-align:center; line-height:150%; padding:.25em;">Wenn nicht anders vermerkt, gelten die angegebenen Daten bei <a href="Standardbedingungen" title="Standardbedingungen">Standardbedingungen</a> (0 °C, 1000 hPa).
</td></tr></tbody></table><p><span class="editoronly" style="display:none;"></span>
</p><p><b>Boroxin</b> (B<sub>3</sub>H<sub>3</sub>O<sub>3</sub>) ist eine <a href="Heterocyclen" title="Heterocyclen">heterocyclische Verbindung</a> aus <a href="Bor" title="Bor">Bor</a> und <a href="Sauerstoff" title="Sauerstoff">Sauerstoff</a>, die auch Cyclotriboroxan genannt wird. Es ist sehr reaktionsfreudig und reagiert schon bei Raumtemperatur spontan mit Sauerstoff und <a href="Kohlenmonoxid" class="mw-redirect" title="Kohlenmonoxid">Kohlenmonoxid</a><sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>.
</p>
<div class="mw-heading mw-heading2"><h2 id="Verwendung">Verwendung</h2></div>
<p>Boroxin dient zur Herstellung von Verbindungen, die für <a href="Elektrolyte" class="mw-redirect" title="Elektrolyte">Elektrolyte</a> von <a href="Lithium-Polymer-Akkumulator" title="Lithium-Polymer-Akkumulator">Lithium-Polymer-Akkumulatoren</a><sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> und für optische Materialien<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> benutzt werden.
</p>
<div class="mw-heading mw-heading2"><h2 id="Derivate">Derivate</h2></div>
<p>Abgeleitete Verbindungen mit der für Boroxin typischen Ringstruktur (B<sub>3</sub>O<sub>3</sub>-R<sub>3</sub>) werden auch <b>Boroxine</b><sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> genannt. Sie können als Anhydride der <a href="Borons%C3%A4ure" class="mw-redirect" title="Boronsäure">Boronsäuren</a> aufgefasst werden. Boroxine entstehen häufig bei Reaktionen von <a href="Bors%C3%A4ure" title="Borsäure">Borsäuren</a>.<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup>
</p>
<ul><li><a href="Trihydroxyboroxin" class="mw-redirect" title="Trihydroxyboroxin">Trihydroxyboroxin</a> (H<sub>3</sub>B<sub>3</sub>O<sub>6</sub>), eine Metaborsäure</li>
<li><a href="Trimethoxyboroxin" title="Trimethoxyboroxin">Trimethoxyboroxin</a> (C<sub>3</sub>H<sub>9</sub>B<sub>3</sub>O<sub>6</sub>)</li>
<li><a href="Trimethylboroxin" title="Trimethylboroxin">Trimethylboroxin</a> (C<sub>3</sub>H<sub>9</sub>B<sub>3</sub>O<sub>3</sub>)</li>
<li>Triarylboroxine<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup></li>
<li><a href="Triphenylboroxin" title="Triphenylboroxin">Triphenylboroxin</a></li>
<li>Tri(4-bromophenyl)boroxin</li>
<li>3-Chlorpropoxyboroxin</li>
<li>2-Chlorethoxyboroxin</li>
<li>2,4,6-Trivinylcyclotriboroxan-Pyridin (CAS-Nummer: <span title="Untervorlage eingebunden: CASRN"></span><span class="KeinCASLink" title="CAS-Nummer ohne Common-Chemistry-Eintrag">95010-17-6</span><span class="editoronly" style="display:none;"></span>)</li></ul>
<p>Die Synthese von Boroxinderivaten erfolgt durch die Kondensation von Borsäuren. Die meisten Boroxine liegen in Anwesenheit von Wasser im Gleichgewicht mit ihren entsprechenden Boronsäuren vor.
</p>
<div class="mw-heading mw-heading2"><h2 id="Einzelnachweise">Einzelnachweise</h2></div>
<ol class="references">
<li id="cite_note-NV-1"><span class="mw-cite-backlink"><a href="#cite_ref-NV_1-0">↑</a></span> <span class="reference-text">Dieser Stoff wurde in Bezug auf seine Gefährlichkeit entweder noch nicht eingestuft oder eine verlässliche und zitierfähige Quelle hierzu wurde noch nicht gefunden.</span>
</li>
<li id="cite_note-2"><span class="mw-cite-backlink"><a href="#cite_ref-2">↑</a></span> <span class="reference-text">G. H. Lee II, R. F. Porter: <cite style="font-style:italic">Gaseous Boroxine: Mechanisms of Reactions with Oxygen and Carbon Monoxide</cite>. In: <cite style="font-style:italic">Inorganic Chemistry</cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em"> </span>5</span>, 1966, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>1329–1333</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1021/ic50042a007">10.1021/ic50042a007</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Boroxin&rft.atitle=Gaseous+Boroxine%3A+Mechanisms+of+Reactions+with+Oxygen+and+Carbon+Monoxide&rft.au=G.+H.+Lee+II%2C+R.+F.+Porter&rft.btitle=Inorganic+Chemistry&rft.date=1966&rft.doi=10.1021%2Fic50042a007&rft.genre=book&rft.pages=1329-1333&rft.volume=5" style="display:none"> </span></span>
</li>
<li id="cite_note-3"><span class="mw-cite-backlink"><a href="#cite_ref-3">↑</a></span> <span class="reference-text">Literaturliste <style data-mw-deduplicate="TemplateStyles:r261891140">
/* start https://de.wikipedia.org/ */
.mw-parser-output .webarchiv-memento a{color:inherit}
/* end https://de.wikipedia.org/ */
</style><a rel="nofollow" class="external text" href="https://web.archive.org/web/20070929102517/http://cheme.eng.shizuoka.ac.jp/~f-klab/f-journal.htm">T. Fujinami</a> (<span class="webarchiv-memento"><a href="Webarchivierung#Begrifflichkeiten" title="Webarchivierung">Memento</a></span> vom 29. September 2007 im <i><a href="Internet_Archive" title="Internet Archive">Internet Archive</a></i>)</span>
</li>
<li id="cite_note-4"><span class="mw-cite-backlink"><a href="#cite_ref-4">↑</a></span> <span class="reference-text">Q. G. Wu, G. Wu, L. Brancaleon, S. Wang: <cite style="font-style:italic">B<sub>3</sub>O<sub>3</sub>Ph<sub>3</sub>(7-azaindole): Structure, Luminescence, and Fluxionality</cite>. In: <cite style="font-style:italic"><a href="Organometallics" title="Organometallics">Organometallics</a></cite>. <span style="white-space:nowrap">Band<span style="display:inline-block;width:.2em"> </span>18</span>, 1999, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>2553–2556</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1021/om990053t">10.1021/om990053t</a></span> (<a rel="nofollow" class="external text" href="https://web.archive.org/web/20070317022931/http://www.chem.queensu.ca/people/faculty/Wu/publication/om990053t.pdf">chem.queensu.ca</a> (<span class="webarchiv-memento"><a href="Webarchivierung#Begrifflichkeiten" title="Webarchivierung">Memento</a></span> vom 17. März 2007 im <i><a href="Internet_Archive" title="Internet Archive">Internet Archive</a></i>) [PDF; <span style="white-space:nowrap">66<span style="display:inline-block;width:.2em"> </span>kB</span>]).<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Boroxin&rft.atitle=B3O3Ph3%287-azaindole%29%3A+Structure%2C+Luminescence%2C+and+Fluxionality&rft.au=Q.+G.+Wu%2C+G.+Wu%2C+L.+Brancaleon%2C+...&rft.btitle=Organometallics&rft.date=1999&rft.doi=10.1021%2Fom990053t&rft.genre=book&rft.pages=2553-2556&rft.volume=18" style="display:none"> </span></span>
</li>
<li id="cite_note-5"><span class="mw-cite-backlink"><a href="#cite_ref-5">↑</a></span> <span class="reference-text"><span class="cite">Patent <a rel="nofollow" class="external text" href="https://www.google.com/patents/US6335423">US6335423</a>: <i>Boroxine compositions.</i> Angemeldet am <span style="white-space:nowrap;">19. März 1998</span>, veröffentlicht am <span style="white-space:nowrap;">1. Januar 2002</span>, Anmelder: <a href="Pilkington" title="Pilkington">Pilkington</a>, Erfinder: Karikath Sukumar Varma (verfallen).</span><span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&rft_id=US6335423&rft.applcc=US&rft.title=Boroxine+compositions&rft.inventor=Karikath+Sukumar+Varma&rft.assignee=%5B%5BPilkington%5D%5D&rft.appldate=1998-03-19&rft.pubdate=2002-01-01"></span></span>
</li>
<li id="cite_note-6"><span class="mw-cite-backlink"><a href="#cite_ref-6">↑</a></span> <span class="reference-text"><a rel="nofollow" class="external text" href="https://web.archive.org/web/20131204130625/http://www.alfa.com/media/pdf/brochures/Boronic%20Acid%20Brochure.pdf">Broschüre von Alfa Aesar</a> (<span class="webarchiv-memento"><a href="Webarchivierung#Begrifflichkeiten" title="Webarchivierung">Memento</a></span> vom 4. Dezember 2013 im <i><a href="Internet_Archive" title="Internet Archive">Internet Archive</a></i>) (PDF; 942 kB)</span>
</li>
<li id="cite_note-7"><span class="mw-cite-backlink"><a href="#cite_ref-7">↑</a></span> <span class="reference-text">G.Alcaraz, L. Euzenat,O. Mongin,C. Katan, I. Ledoux, J. Zyss, M. Blanchard-Desce, M. Vaultier: <cite style="font-style:italic">Improved transparency–nonlinearity trade-off with boroxine-based octupolar molecules</cite>. In: <cite style="font-style:italic"><a href="Chemical_Communications" title="Chemical Communications">Chemical Communications</a></cite>. 2003, <span style="white-space:nowrap">S.<span style="display:inline-block;width:.2em"> </span>2766–2767</span>, <a href="Digital_Object_Identifier" title="Digital Object Identifier">doi</a>:<span class="uri-handle" style="white-space:nowrap"><a rel="nofollow" class="external text" href="https://doi.org/10.1039/b308664j">10.1039/b308664j</a></span>.<span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rfr_id=info:sid/de.wikipedia.org:Boroxin&rft.atitle=Improved+transparency-nonlinearity+trade-off+with+boroxine-based+octupolar+molecules&rft.au=G.Alcaraz%2C+L.+Euzenat%2CO.+Mongin%2C+...&rft.btitle=Chemical+Communications&rft.date=2003&rft.doi=10.1039%2Fb308664j&rft.genre=book&rft.pages=2766-2767" style="display:none"> </span></span>
</li>
</ol></div><!--htdig_noindex--><div><div class="zim-footer">
Dieser Artikel wurde von <a class="external text" title="Zuletzt bearbeitet am 2024-08-22" href="https://de.wikipedia.org/wiki/?title=Boroxin&oldid=247955484">Wikipedia</a> herausgegeben. Der Text ist unter <a class="external text" href="https://creativecommons.org/licenses/by-sa/4.0/deed.de">Creative Commons Attribution-Share Alike 4.0</a> verfügbar, sofern nicht anders angegeben. Für die Mediendateien können zusätzliche Bedingungen gelten.
</div>
</div><!--/htdig_noindex--></div>
</div>
</main>
</div>
</div>
</div>
<script src="./_webp_/webpHandler.js"></script>
</body></html>